Synthesis and Structural Investigation of Nano-Sized Cadmium Ferrite

  • Rakesh M. Shedam Department of Physics, GKG college, Kolhapur 416012
  • Ashok B. Gadkari Department of Physics, GKG college, Kolhapur 416 012
  • Shridhar N Mathad K.L.E. Institute of technology, Hubli 580030, India
  • Mahadev R. Shedam The New College, Kolhapur 416 012

Abstract

This report presents the synthesis of cadmium ferrite (CdFe2O4) by Oxalate co-precipitation and its subsequent characterization by using X-ray diffraction (XRD) and Fourier transform Infrared spectroscopy (FTIR) techniques. XRD results confirm the single cubic spinel phase formation with lattice parameter 8.7561Ao. An infrared spectroscopy study shows the presence of main two absorption bands indicating the presence of tetrahedral and octahedral group complexes, respectively, within the spinel lattice. We also report strain, hopping length (LA and LB) and dislocation density  of ferrite sample.

Keywords: Cadmium ferrite (CdFe2O4), XRD, Dislocation density, Strain, SEM

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References

R. F. Soohoo, “Theory and Application of Ferrites”, Prentice-Hall, 1960

Goldman, Alex, “Modern Ferrite Technology”, DOI 10.1007/978-0-387-29413-1, Springer-Verlag US

E.C.Snelling,. “Soft Ferrites: properties and applications”, Published by Iliffe Books, London (1969) ,ISBN 10: 0592027902 ISBN 13: 9780592027906

R. E. Collin, “Foundations for Microwave Engineering”, 2nd Ed., IEEE Press, 2000

Ü. Özgür, Y. Alivov, and H. Morkoç, “Microwave Ferrites, Part 2: Passive components and electrical tuning”, J. Mater. Sci.: Materials in Electronics, vol.20,no.10,pp.911-952 · October 2009

Harris, V.G., “Advances in magnetics: Modern microwave ferrites”, IEEE Trans. Magn., , vol. 48, no. 3,pp. 1075–1105 , 2012

B. K. Bommannavar, L. R. Naik and R. B. Pujar and B. K. Chougule, “Preparation and characterization and physical properties of Mg-Zn ferrites, Indian Journal of Engineering and Materials Science vol.14, pp 381-385 ,2007

V.Sepelak, K. Baabe, K.Mienert, K.Schultze, F.Krumeich, F.J.Litterst, K.D.Becker, “Evolution of structure and magnetic properties with annealing temperature in nanoscale high-energy-milled nickel ferrite”,J.Magn. Magn. Mater. vol.257, pp.377-386, 2003

J.Zhu, D.Xiao, J.Li, X.Yang, Y.Wu, “Characterization of FeNi3 alloy in Fe–Ni–O system synthesized by citric acid combustion method”, Scr.Mater. vol.54 (109-113. 2006

S.N.Mathad , R. N. Jadhav ,R.P.Pawar , V. Puri “Electromagnetic Behavior of Lead FreeFerroelectrics at Microwave Frequencies”,Advanced Science Engineering and Medicine, Vol. 5, pp. 1–7,2013

M.R.Patil, M.K.Rendale, S. N.Mathad and R.B.Pujar, “Structural and IR study of Ni0.5–XCdXZn0.5Fe2O4”, International Journal of Self-Propagating High Temperature Synthesis, , Vol. 24, No. 4, pp. 241–245, 2015

M.K.Shobana, S.Sankar, “Structural, thermal and magnetic properties of Ni1−xMnxFe2O4 nanoferrites” J.Magn.Magn.Mater. vol.321,no.14 2125-2128, 2009

A.T.Pathan ,S.N.Mathad ,A. M. Shaikh, “Infrared Spectral studies of Co2+ substituted LiNi-Zn Nano-structured Ferrites”, International Journal of Self-Propagating High Temperature Synthesis, Vol. 23, No. 2, pp. 112–117,2014

S.M.Patange, S.E.Shirsath, S.S.Jadhv, K.S.Lohar,D.R.Mane, K.M.Jadhv, “Structural, morphological and hydrophilic properties of nanocrystalline NiFe2O4 by combustion route”Mater. Lattr. vol.64 pp722-724,2010

S.S.Yattinahalli, S.N.Mathad, S.B.Kapatkar, “Structural Studies of Zinc Ferrite Synthesized at Low Temperature”, International Review, vol.1,no.1, pp.5-8, June 2014.

S.S.Yattinahalli,S.B.Kapatkar S.N.Mathad, “Structural and mechanical properties of a nano ferrite” , Advanced Science Focus, Vol. 2, pp. 42–46, 2014

L.Guo, X.Shen, X.Meng, Y.Feng, “Effect of Sm 3+ ions doping on structure and magnetic properties of nanocrystalline NiFe2O 4 fibers”J.Alloy Compd, vol.490 pp.301-306,2010

Sachin V. Bangale, S. R. Bamane, “Synthesis characterization and electrical properties of nanocrystalline ZnMgO by combustion route” Der Chemica Sinica, vol.2,no.5, pp.22-29,2011

L.Chena, H.Dai, Y.Shen, J.Bai, “Composition and film thickness effects on microstructure and magnetic properties of ordered L10-structured Fe100−xPtx films” J.Alloy Compod. vol.491,pp.33-38,2010

N.Z.Bao, L.M.Shen, Y.H.Wang, P.Padhan, A.Gupta, “A Facile Thermolysis Route to Monodisperse Ferrite Nanocrystals”, J. Am. Chem. Soc., , vol.129,no.41, pp 12374–12375 , 2007

Mathad, S.N. and Puri, V., Microwave studies of environmental friendly ferroelectrics, Int. Schol. Res. Notices, , vol. 2014, article ID 683986. 2014

Mathad, S.N., Jadhav, R.N., Patil, N.D., and Puri, V., Structural and mechanical properties of Sr+2 doped bismuth manganite thick films, Int. J. Self-Propag. High-Temp. Synth., , vol. 22, no. 4, pp. 180–184,2013

Wurst, J.C. and Nelson, J.A., “Lineal intercept technique for measuring grain size in two-phase polycrystalline ceramics”J. Am. Ceram. Soc. Bull., , vol. 55, no. 1, pp. 109–111, 1972

R. Iyer, R. Desai, and R. V. Upadhyay, “Low temperature synthesis of nanosized Mn1-xCdxFe2O4 ferrites” Ind. J. Pure App. Phy. vol.47, pp.180-185, ,2009.

S. Zahi, “Synthesis, “Permeability and Microstructure of the Optimal Nickel-Zinc Ferrites by Sol-Gel Route”, J. Electromagnetic Analysis & Applications, , vol.2, pp.56-62, 2010

S.N.Mathad , R. N. Jadhav ,R.P.Pawar , V. Puri “Electromagnetic Behavior of Lead Free Ferroelectrics at Microwave Frequencies”,Advanced Science Engineering and Medicine, Vol. 5, pp. 1–7,2013

Published
2016-10-01
How to Cite
[1]
R. Shedam, A. Gadkari, S. Mathad, and M. Shedam, “Synthesis and Structural Investigation of Nano-Sized Cadmium Ferrite”, J. Mod. Mater., vol. 2, no. 1, pp. 7-12, Oct. 2016.
Section
Research Article